Exothermic vs endothermic
Exothermic reactions transfer energy TO the surroundings, so the surroundings get hotter and is negative — e.g. combustion, neutralisation, a reactive metal with acid. Endothermic reactions take energy IN from the surroundings, so they get colder and is positive — e.g. thermal decomposition of a carbonate, photosynthesis. Each definition scores one mark for the energy direction and one for the temperature change of the surroundings.
Heat energy — Q = mcΔT
gives the heat energy transferred to the water: in joules (J), = mass of the WATER heated in grams (g), = specific heat capacity of water , and = temperature change in °C. Always use the mass of the water, never the mass of fuel, and find first (highest reading minus start). The result is in joules — divide it by 1000 later to reach kilojoules for the molar enthalpy step.
Molar enthalpy — ΔH = Q ÷ moles
is the molar enthalpy change in kJ/mol, where = moles of the fuel or limiting reactant () and dividing by 1000 converts joules to kilojoules. The sign is part of the answer: is negative for exothermic (energy leaves the chemicals) and positive for endothermic. Example: released by of fuel gives .
Drawn from real examiner reports.
Vague energy definitions lose the mark
Writing only "exothermic gives out heat" or "endothermic takes in heat" can be marked incomplete, and reversing the temperature direction is a frequent error. Tie the energy transfer to a measurable change: exothermic transfers energy TO the surroundings, so their temperature RISES; endothermic takes energy IN, so their temperature FALLS.
Fuel ≠ "a source of energy"
Defining a fuel as merely "a source of energy" scores zero. A creditworthy definition needs BOTH ideas: the substance burns / combusts, AND it releases heat (thermal) energy. "Source of energy" is too vague because it names neither the combustion nor the heat released — both are required for the mark.
Jun24 1CR Q6a
Exothermic ΔH must be negative
For an exothermic reaction must carry a negative sign — energy leaves the chemicals. Writing for a combustion loses the final mark because a positive value is endothermic. A correct magnitude with the wrong sign, or without the required significant figures, still drops marks — check both.
Jun23 Q8cii; Jun24 1CR Q6biii
"Energy lost" is too vague
When explaining why the experimental is less exothermic than the true value, "energy lost" or "energy escaped" is too vague and scores zero. Name the pathway: heat lost to the surroundings. Also creditworthy are incomplete combustion of the fuel and heat absorbed by the metal can. "Human error" and "misread the thermometer" earn nothing.
Jun24 1CR Q6c
Add the rise, don't subtract
To find the highest temperature, ADD the temperature rise to the starting temperature; some candidates wrongly subtract the two readings. When finding for an exothermic change it is highest reading minus start; for a cooling (endothermic) change it is start minus lowest reading. Get the direction right before substituting into .
Jun24 1CR Q6bi
Use the mass of water, not fuel
In the mass is the mass of the WATER being heated, never the mass of fuel burned. The fuel mass is used only later, to find the moles () for the step. Putting the fuel mass into gives a tiny, wrong heat value and loses the accuracy mark.
Follow the four-step chain
Work calorimetry in a fixed order: (1) = highest minus start; (2) with the mass of water and ; (3) moles ; (4) . Doing the steps out of order is where slips creep in.
Show every substitution (ECF)
Write the formula and the numbers substituted at each step. If you slip in one step, the examiner can still award the method marks for the others (error carried forward). An answer with no working, or a bare number, forfeits marks on "show that" and calculation questions.
Round only at the end
Keep full calculator figures through the intermediate steps and round only the final answer, to the number of significant figures the question asks for. Truncating a value mid-calculation (e.g. moles to 1 s.f.) shifts the final answer and loses the accuracy mark.
Exothermic reaction — a reaction that transfers energy to the surroundings, so the temperature of the surroundings rises. (Two elements: energy out + surroundings get hotter.) Examples: combustion, neutralisation, most oxidation, reactive metal + acid.
Endothermic reaction — a reaction that takes in energy from the surroundings, so the temperature of the surroundings falls. (Two elements: energy in + surroundings get colder.) Examples: thermal decomposition, photosynthesis, citric acid + sodium hydrogen carbonate.
Fuel — a substance that releases heat (thermal) energy when it is burned (combusted).
Key formulae:
| Quantity | Formula | Meaning of symbols |
|---|---|---|
| Heat energy change | = heat energy (J); = mass of water (g); = specific heat capacity of water ; = temperature change (°C) | |
| Moles | = amount (mol); = mass (g); = relative formula mass | |
| Molar enthalpy change | = enthalpy change (kJ/mol); divide by 1000 to convert J to kJ; negative for exothermic, positive for endothermic |
Define an exothermic reaction.
In a calorimetry experiment, of water is heated by a burning fuel. The temperature of the water rises from to .
The specific heat capacity of water is .
Calculate the heat energy transferred to the water, . Give the unit.