Rusting — needs oxygen AND water
Rusting is the corrosion of iron/steel to hydrated iron(III) oxide, — is variable, so no fixed value is required. It needs both oxygen and water together: a nail under boiled, cooled water sealed with oil (water, no oxygen) does not rust; a nail in air dried with anhydrous calcium chloride (oxygen, no water) does not rust; a nail in moist air does. Nitrogen, 78% of air, is unreactive and is never a condition to name.
Barrier methods — paint, grease, plastic
A barrier method coats the iron in a continuous physical layer so oxygen and water cannot reach the metal: painting (gates, car bodies, bridges), greasing/oiling (bicycle chains, tools, hinges — moving parts where paint is impractical) and plastic coating, e.g. PVC (coat-hangers, dish-drainer racks). Rusting needs both at the surface, so excluding them stops it — but only while the layer stays unbroken. A scratch or worn patch reopens the iron there.
(Extended) Galvanising — barrier and sacrificial
Galvanising coats steel (an iron alloy) with zinc, giving two mechanisms at once. (1) Barrier: the zinc excludes oxygen and water while intact, like paint. (2) Sacrificial protection: zinc lies above iron in the reactivity series, so it loses electrons more readily — . At a scratch zinc is oxidised in preference to iron, so the iron does not rust while zinc remains. Unlike paint, it keeps working after damage.
Drawn from real examiner reports.
"Rusts in air" leaves out water
"Iron rusts in air" is not credited: it never names oxygen specifically, and it omits water entirely. Naming only water is equally incomplete. The mark-scheme answer is that oxygen and water must both be present. Each is necessary and neither alone is sufficient — remove either and no rust forms. Nitrogen takes no part, so it is never a condition to state.
Nov 2023 P13 Q25, P43 Q2d
(Extended) Barrier ≠ sacrificial protection
Asked why galvanised steel resists rust where the coating is scratched, candidates restate the barrier idea — "the zinc keeps oxygen and water out". That holds only while the coating is intact. The scratched case needs sacrificial protection: zinc is more reactive, so at the exposed metal zinc is oxidised instead of iron. Paint has no such backup.
Nov 2023 P13 Q25, P43 Q2d
(Extended) "More reactive" = loses electrons
"More reactive" here does not mean fizzing harder with acid or burning more fiercely. For sacrificial protection it means the metal loses electrons more readily to form its positive ion: zinc forms more readily than iron forms or , so zinc is oxidised in preference. Oxidation is loss of electrons; reduction is gain.
Redox vocabulary flagged Jun 2022 P23 Q18; Jun 2023 P11 Q20; Nov 2023 P43 Q11aii
"Paint stops rust" is not a mechanism
"The paint stops the rust" describes the outcome, not the mechanism, and scores nothing on a describe how question. The required chain is: the coating forms a continuous physical layer over the iron, this excludes oxygen and water, and without both rusting cannot occur. Name the layer, name what it keeps out, then link back to the conditions.
Each tube must remove one condition
In the three-test-tube experiment every tube must remove exactly one condition. Candidates draw the deoxygenated tube without the layer of oil sealing it, so air redissolves, and label the drying agent vaguely instead of naming anhydrous calcium chloride (or silica gel) removing water vapour. Without those labels no tube isolates a single variable.
Match the command word
State wants the bare conditions or the method name; describe wants what happens; explain wants the reason why. Then count your points against the tariff — a 3-mark "describe how" needs three distinct scoring ideas, not one idea rephrased three times.
(Extended) Spot the word "scratched"
Scan the stem for "scratched", "damaged" or "chipped". If the coating is broken, a barrier answer earns nothing — switch to sacrificial protection (zinc is more reactive, so it is oxidised in preference to iron). If the coating is intact, the barrier mechanism is the one wanted.
Build ionic formulae by balancing charge
Build an ionic formula by balancing total charge, not by copying the number of ion types named. The oxide in rust comes from and : two give 6+, three give 6-, so it is . "FeO" is the classic slip.
(Extended) Half-equations balance charge too
A half-equation must balance atoms and charge. In the two electrons cancel the 2+, leaving both sides neutral. Leaving the electrons off unbalances the charge and throws away the mark they carry.
Cambridge 0654 spec reference: Section C9 "Metals", sub-topic C9.5 "Corrosion of metals". Core: state the conditions required for iron to rust (oxygen and water); state common barrier methods (painting, greasing, plastic coating); describe how barrier methods prevent rusting by excluding oxygen and water. Extended (Supplement): describe zinc used in galvanising steel as an example of BOTH a barrier method AND sacrificial protection; explain sacrificial protection via the reactivity series and electron loss.
| Term | Mark-scheme-precise meaning |
|---|---|
| Rusting | The corrosion of iron/steel to form hydrated iron(III) oxide (); occurs only when BOTH oxygen AND water are present together |
| Barrier method | A rust-prevention method that coats the iron/steel surface with a continuous physical layer (e.g. paint, grease/oil, plastic), excluding oxygen and water from the metal underneath |
| Galvanising | Coating steel with a layer of zinc, which protects the iron BOTH as a barrier method AND by sacrificial protection |
| Sacrificial protection | Protecting iron by coating/attaching it to a MORE REACTIVE metal (e.g. zinc), which is oxidised (loses electrons) in preference to the iron, even where the coating is damaged |
Define a barrier method of rust prevention.
Rust contains iron(III) ions () and oxide ions ().
Write the formula of the iron oxide component of rust. (1 mark)