Alkali metals -- lithium, sodium, potassium
Group I, the alkali metals, is the first column of the Periodic Table; the syllabus names lithium (Li), sodium (Na) and potassium (K). Each atom has one electron in its outer shell, readily lost to form a 1+ ion -- the source of the group's shared chemistry. They are relatively soft: cut with a knife to reveal a shiny surface that tarnishes rapidly in air, which is why they are stored under oil. All three are less dense than water, so they float on it.
Trends down the group, Li to K
Going from lithium to potassium: melting point decreases (Li , Na , K ); density shows a general increase; reactivity with water increases. The observations are the evidence: lithium fizzes steadily without melting, sodium melts instantly into a ball and moves rapidly while fizzing vigorously, potassium melts and ignites with a lilac flame.
Reaction with water, and why it speeds up
Every Group I metal reacts the same way -- alkali metal + water metal hydroxide + hydrogen -- i.e. (M = Li, Na, K). The alkaline hydroxide solution names the group. Reactivity rises down the group because each element gains an electron shell: the outer electron is further from the nucleus and shielded by more inner shells, so it is held less strongly and lost more easily.
Drawn from real examiner reports.
Group I trends stated backwards
Two trends are routinely reversed: melting point said to increase down the group (importing a "bigger atom, higher melting point" idea that does not apply here), and reactivity with water said to decrease. Fix the directions once and use them together: from lithium down to potassium melting point falls, density generally rises, and reactivity with water rises.
Jun 2023 P43 Q5a; Nov 2023 P13 Q22
Name every trend the marks ask for
"Describe how the properties change down Group I" normally carries a mark per trend, but candidates give reactivity alone -- the memorable one -- and drop melting point and density. Match the number of directed statements to the tariff: melting point decreases, density generally increases, reactivity with water increases. One trend reworded three ways scores once.
Jun 2023 P43 Q5a; Nov 2023 P13 Q22
"Very reactive" is not a definition
Calling an alkali metal simply "a very reactive metal" describes a consequence, not the definition, and earns little credit. Two structural parts are needed: the element is a metal in the first column (Group I) of the Periodic Table, and each atom has one electron in its outer shell, readily lost to form a 1+ ion. That outer electron is why the group behaves alike.
Density rises only in general
The expected trend is a general increase in density down Group I, not a perfectly regular one: potassium () is very slightly less dense than sodium (). Say "general increase" whenever data is supplied, or the dip looks like a contradiction. Melting point and reactivity, by contrast, are regular across Li, Na and K.
Restating the observation is not explaining
"Explain why potassium reacts more vigorously than sodium" is not answered by repeating the observation ("it reacts faster", "it ignites") or by vague energy talk. The marks sit in the electron-structure chain: one more electron shell, so the outer electron is further from the nucleus and shielded by more inner shells, so it is held less strongly and lost more easily.
(Extended) A Group I hydroxide is MOH
A predicted Group I element still forms a 1+ ion, so its hydroxide pairs one M with one OH in a 1:1 ratio: RbOH, CsOH -- never RbOH or RbOH. Do not import a 2+ charge by analogy with another group. The same 1:1 logic is what keeps the equation at .
Group I trend is not the Group VII trend
Group I reactivity increases down the group -- bigger atoms lose their single outer electron more easily. Group VII reactivity decreases down the group -- bigger atoms gain an extra electron less easily. Opposite directions for opposite reasons (losing versus gaining an electron). Borrowing the halogen trend is the usual source of a reversed Group I answer.
(Extended) Extrapolate in three steps
(Extended) Compare, do not invent a number
Unless exact data is supplied, answer comparatively: "lower than potassium", "reacts more vigorously than rubidium, most likely igniting at once". A guessed absolute value is unsupported and easily wrong, while a directed comparison tied to the stated trend is fully creditable.
Check coefficients and state symbols
In it is the 2 in front of water that balances the H produced -- the most commonly dropped coefficient. The hydroxide is (aq), because it dissolves in the excess water, not (s).
One distinct observation per mark
"Describe what you would see" wants different observations, not one restated: floats, melts into a ball (or does not melt), speed of movement, fizzing/gas given off, and for potassium ignition with a lilac flame. Count the marks available and supply that many distinct points.
Cambridge 0654 spec reference: Section C8 "The Periodic Table", sub-topic C8.2 "Group I properties". Core: describe the Group I alkali metals lithium, sodium, potassium as relatively soft metals, with general trends down the group -- decreasing melting point, increasing density, increasing reactivity with water. (Ext): predict properties of other Group I elements given information about the elements.
| Term | Mark-scheme-precise meaning |
|---|---|
| Group I / alkali metals | The metals in the first column of the Periodic Table -- lithium, sodium, potassium (and, further down, rubidium, caesium, francium) -- each atom having one electron in its outer shell |
| Alkali metal | A Group I metal, named because it reacts with water to form an alkaline solution (a metal hydroxide) plus hydrogen gas |
| Relatively soft metal | Soft enough to be cut with a knife, exposing a shiny surface that tarnishes rapidly in air |
General reaction with water (M = Li, Na or K): (word equation: alkali metal + water metal hydroxide + hydrogen)
Define a "Group I metal" (alkali metal).
A small piece of potassium is added to a trough of water. It floats, melts, moves rapidly across the surface and ignites, burning with a lilac flame, producing potassium hydroxide solution and hydrogen gas.
Write the balanced symbol equation for this reaction, including state symbols. (3 marks)