Molecular formula — atoms in one molecule
The subscript after each symbol gives that element's atom count; a subscript of 1 is never written. A molecular formula gives the actual number of atoms of each element in one molecule — not a ratio, and not just the element names. Seven elements are diatomic and always carry subscript 2: , , , , , , . Deduce a formula from a model by counting every atom shown.
Word vs symbol equations — and coefficients
A word equation uses full names only. A symbol equation uses formulas and must be balanced: the same atom count of each element on both sides, because atoms are conserved. Balance only by changing coefficients — the large number in front of a whole formula. Work one element at a time, starting with the one in the fewest formulas and leaving free diatomics until last, then re-check every element. A state symbol — (s), (l), (g), (aq) — follows every formula.
(Extended) Ionic formula unit — zero overall charge
Ionic compounds form a giant lattice, not molecules, so the formula is a formula unit: the simplest whole-number ratio of ions giving an overall charge of zero. Criss-cross the charge magnitudes, ignoring sign, so each becomes the other ion's subscript, then simplify. A polyatomic ion — one made of more than one element, e.g. , , , — needs brackets before a subscript above 1.
Drawn from real examiner reports.
Diatomic element written as one atom
Seven elements exist as diatomic molecules and their formula always carries subscript 2. Writing "N" for nitrogen gas — or "2N", which is a coefficient describing two separate atoms, not the molecule — puts half the correct atom count on that side. Knowing the word "diatomic" is not enough: it means two atoms of that element bonded in one molecule.
Flagged Jun 2022 P16 Q16; P42 Q8aii · Nov 2023 P11 Q15
Word equation written with formulae
When the question says word equation, only the full names of the reactants and products earn credit: "magnesium + oxygen magnesium oxide". A formula, or a name-and-formula mixture, does not answer the command as set, even when the chemistry is right. The reverse fails too — names written inside what should be a balanced symbol equation.
Flagged Nov 2022 P31 Q8bi · Jun 2023 P31 Q11bi
Counting elements vs counting atoms
contains 3 elements (Ca, C, O) and 5 atoms (); contains 3 elements and 7 atoms (). Candidates read the subscript 3 off as the atom total, or count only the symbols they can see. Elements = how many different symbols; atoms = the subscripts added up, an unwritten subscript counting as 1.
Flagged Jun 2023 P32 Q11c · Nov 2023 P31 Q11b
Balancing by rewriting the formulas
Balance only with coefficients placed in front of whole formulas. Changing a subscript makes a different substance — and are not the same compound — and tacking an extra molecule onto one side is not balancing either; adjust the coefficient. Re-check every element at the end: fixing one often unbalances one already correct.
Flagged Jun 2022 P41 Q2b · Nov 2023 P41 Q2c
State symbols on only some species
"Including state symbols" means one on every species, reactants and products alike — a correctly balanced equation with two of four states missing still drops the marks for states. A precipitate is (s), not (aq): it is insoluble and has left the solution. A substance dissolved in water is (aq); (l) is reserved for a pure liquid.
(Extended) Criss-cross applied backwards
with gives , not . The cation's charge magnitude becomes the anion's subscript and vice versa — swapping them is the standard slip. Check by totalling the charges: balances . If the two totals do not cancel, the subscripts are the wrong way round.
(Extended) Polyatomic ion left unbracketed
with is , never "NH42SO4"; with is , never "CaOH2". Without brackets the subscript attaches to the last atom of the ion alone, so the formula states a different substance. Bracket any polyatomic ion before giving it a subscript above 1.
Match the command word
"State the formula" wants the formula alone. "Define molecular formula" wants both halves — the actual number of atoms of each element, in one molecule. "Deduce" wants a formula built by counting what the model shows, with working. "Construct a word equation" wants names only.
Balance in a fixed order, then state-symbol
Write correct formulas, then balance elements in only one formula per side, leaving free diatomics until last. Re-check every element. For combustion: C, then H, then halve the right-hand oxygen total for the coefficient. Finish with a state symbol on every species.
(Extended) Build an equation from a description
Constructing an equation from given information is more than balancing a printed one: name every reactant and product with its state, write each correct formula, then balance. For an ionic equation, cancel the spectator ions — those unchanged in solution before and after.
Cambridge 0654 spec reference: Section C3 "Stoichiometry", sub-topic C3.1 (Core + Extended). This leaf covers the Core ideas of naming formulas, defining a molecular formula, deducing a molecular formula from a model/diagram, constructing word equations, and balancing/interpreting simple symbol equations with state symbols; and the Extended ideas of deducing an ionic compound's formula from ion charges, and constructing symbol equations (including ionic equations) with state symbols from given information.
Scope note: the mole, calculations and molar gas volume are NOT part of this leaf -- they belong to C3.3 "The mole and the Avogadro constant" (Extended only in 0654). This leaf is about writing and balancing formulas and equations, not calculating with them.
| Term | Mark-scheme-precise meaning |
|---|---|
| Formula | Symbols and subscript numbers showing which elements a substance contains and in what ratio |
| Molecular formula (Core) | Shows the actual number of atoms of each element present in one molecule of a substance |
| Word equation (Core) | Names of reactants and products written in full words, joined by an arrow -- no formulas |
| Symbol equation (Core) | Formulas of reactants and products, balanced so atoms are conserved, each with a state symbol |
| State symbol (Core) | solid, liquid, gas, aqueous -- written after each formula |
| Ionic formula / formula unit (Extended) | The simplest whole-number ratio of ions giving an overall charge of zero |
| Ionic equation (Extended) | A symbol equation showing only the ions/species that actually change; spectator ions are cancelled |
Diatomic elements (formula always has subscript 2): , , , , , , .
Common formulas to know: water , carbon dioxide , methane , ammonia , hydrogen chloride , sulfuric acid , sodium hydroxide , sodium chloride , calcium carbonate .
(Core) Define molecular formula.
Magnesium burns in oxygen to form magnesium oxide.
(a) (Core) Write a word equation for this reaction. (1 mark)
(b) (Core) Write a balanced symbol equation for this reaction, including state symbols. (3 marks)