Cations lose electrons, anions gain
A cation is a positively charged ion, formed when a metal atom loses outer-shell electrons: Na () becomes (, the neon structure). An anion is a negatively charged ion, formed when a non-metal atom gains electrons: Cl () becomes (, the argon structure). Both end with a full outer shell. Groups I/II/III lose 1/2/3 electrons; Groups VI/VII gain .
Ionic bond = electrostatic attraction
An ionic bond is a strong electrostatic attraction between oppositely charged ions. One or more electrons transfer from a metal atom to a non-metal atom; the metal becomes a cation, the non-metal an anion, and the opposite charges attract strongly. Core examines Group I with Group VII (Na + Cl). Extended generalises this to metallic and non-metallic elements: Mg + O gives 1:1 MgO, Mg + Cl gives 1:2 .
Ionic properties and the giant lattice
Ionic compounds have high melting and boiling points, conduct well when molten or aqueous but poorly when solid, and are generally soluble in water — water molecules separate the oppositely charged ions out of the lattice. (Extended) They form a giant lattice: a regular arrangement of alternating positive and negative ions throughout the solid, e.g. NaCl. Melting overcomes very many strong attractions; conduction needs ions free to move.
Drawn from real examiner reports.
Ionic bond ≠ sharing electrons
"Atoms sharing electrons" or "atoms joined together" describes covalent bonding and scores zero for an ionic bond. The mark scheme needs both halves: electrostatic attraction (not "sharing", not a vague "joining") and oppositely charged ions (not "atoms"). Name the attraction, and name the ions it acts between.
Flagged Nov 2022 P42 Q2vi/vii; Jun 2023 P41 Q5bi
Dot-and-cross: draw ions, not arrows
Diagrams must show the resultant ions — each with the right outer-shell electron count, in square brackets with the charge outside — not an arrow showing an electron jumping across, and not neutral atoms left unrelabelled. Shell sizes and spacing must stay consistent. For draw two separate chloride ions, one electron to each, not both to one chlorine.
Flagged Nov 2022 P42 Q2vi/vii; Jun 2023 P41 Q5bi
Metal + halogen is ionic, not covalent
Halogens are non-metals, so candidates extend the "non-metal means covalent" rule to every bond a halogen forms. Bond type depends on both elements: two non-metals give covalent (, HCl); a metal with a non-metal gives ionic (NaCl). Chlorine does both, so check its partner before choosing.
Flagged Nov 2023 P32 Q2a
(Extended) "Strong bonds" is too vague
Asked to explain a high melting point, "it has strong bonds" or "the particles are close together" does not score. Name the giant lattice, the strong electrostatic attractions between oppositely charged ions, that melting overcomes very many of them throughout the structure, and that this needs a large amount of energy.
Flagged Jun 2023 P42 Q8e
(Extended) Ionic lattice ≠ intermolecular forces
The other melting-point error is reaching for the wrong bonding model — describing the strength of covalent bonds within a molecule, or the weak intermolecular forces between molecules, when the question is about an ionic lattice. Keep the three models separate; only the lattice answer earns the marks here.
Flagged Jun 2023 P42 Q8e
(Extended) Solid ionic compounds are still charged
Saying a solid ionic compound "has no charge" is wrong — it is built entirely from charged ions. What it lacks is mobility: the ions are locked in fixed lattice positions and cannot move to carry charge. Melting or dissolving breaks the lattice down so the same ions become free to move, and only then does it conduct.
Ion structure ≠ atom structure
After transfer, quote the ion's electronic structure, not the atom's. is (not ) because the outer electron has gone; is (not ) because one has been gained. Writing the atom's structure beside an ion symbol loses the mark even when the charge itself is right.
Building an ionic formula
Write each ion's charge, then find the smallest whole-number ratio giving zero total charge: cross-multiply and cancel. Do not write charges in as subscripts (); cancel to MgO. Cation first; bracket a polyatomic ion taking a subscript ().
Describing ion formation in three steps
State how many electrons transfer, and in which direction (metal to non-metal); name each resultant ion with its charge, e.g. one and two ; then say the oppositely charged ions attract by strong electrostatic attraction, forming the bond.
Dot-and-cross conventions
Draw outer shells only. Use dots for one element and crosses for the other so the marker can see where each electron came from. Enclose every final ion in square brackets with its charge outside the bracket. Draw as many of each ion as the formula needs.
Match describe vs explain
Core asks you to describe the properties — state them. Extended asks you to explain them in terms of structure and bonding, which means naming the giant lattice, the ions and the electrostatic attraction. Match the number of points you give to the mark tariff.
Cambridge 0654 spec reference: Section C2 "Atoms, elements and compounds", sub-topic C2.4. Core covers the formation of cations and anions, the definition of an ionic bond, ionic bonding between Group I and Group VII elements with dot-and-cross diagrams, and the properties of ionic compounds. Extended (Supplement) adds ionic bonding between metallic and non-metallic elements generally, explaining those properties in terms of structure and bonding, and the giant lattice structure.
| Term | Mark-scheme-precise meaning |
|---|---|
| Cation | A positively charged ion, formed when an atom loses one or more electrons |
| Anion | A negatively charged ion, formed when an atom gains one or more electrons |
| Ionic bond | A strong electrostatic attraction between oppositely charged ions |
| Ionic compound | A compound made of a giant lattice of oppositely charged ions held together by ionic bonds |
| Giant (ionic) lattice (Ext) | A regular arrangement of alternating positive and negative ions, extending throughout the solid, e.g. sodium chloride |
How ions form: a metal atom loses its outer-shell electron(s) to become a cation; a non-metal atom gains electron(s) into its outer shell to become an anion. Both end up with a full outer shell -- the same electronic structure as the nearest noble gas.
Constructing an ionic formula: the total positive and negative charge must balance to zero. The number of each ion needed equals the magnitude of the other ion's charge (cancel any common factor). E.g. with : one balances two , giving .
Properties of ionic compounds (Core: describe; Extended: explain via structure and bonding):
| Property | Core description | Extended explanation |
|---|---|---|
| High melting/boiling points | Ionic compounds have high m.p./b.p. | A giant lattice is held by very many strong electrostatic attractions between oppositely charged ions; a large amount of energy is needed to overcome them |
| Electrical conductivity | Good when aqueous/molten; poor when solid | Conduction needs charged particles free to move; ions are fixed in the solid lattice but free to move when molten or dissolved |
| Solubility | Generally soluble in water | (Core description only -- no Extended explanation required) |
Define cation.
Magnesium forms a ion and oxygen forms an ion. Determine the formula of magnesium oxide. (1 mark)