Celsius, Kelvin, and T/K = θ/°C + 273
Two scales: Celsius (°C), fixed by the ice point (0 °C) and steam point (100 °C); Kelvin (K), the absolute scale where 0 K is absolute zero (particles at minimum energy) and 0 K = −273 °C. Convert with : 100 °C = 373 K; 300 K = 27 °C; −40 °C = 233 K. A change of 1 °C equals a change of 1 K, so in °C equals in K.
Specific heat capacity: E = mcΔθ
Specific heat capacity = energy to raise the temperature of 1 kg by 1 °C (both elements needed). Unit: J/(kg °C). Formula : = energy (J), = mass (kg), = temperature change (°C or K). Cambridge uses for Celsius and for Kelvin. Water J/(kg °C), aluminium J/(kg °C); water's high lets it absorb much energy for a small rise, making it a good coolant.
No temperature change during a state change
At the melting or boiling point energy breaks intermolecular bonds, not the average kinetic energy — so temperature stays constant, a plateau on a temperature–time graph. Melting is solid → liquid, boiling liquid → gas; freezing and condensing are the reverse. (E) Phase-change energy , = specific latent heat (J/kg): fusion (water J/kg) and vaporisation (water J/kg); .
Drawn from real examiner reports.
Δθ is the change, not the final temperature
in is final − initial, not the final temperature. Warming from 15 °C to 65 °C gives °C, not 65 °C. Using the final temperature instead of the change is the single most common arithmetic error in this topic and loses the answer mark.
Evaporation, boiling and condensation differ
Evaporation happens at the surface, at any temperature and cools the liquid (the fastest molecules escape, lowering average KE). Boiling happens throughout the liquid, only at the boiling point. Condensation is the reverse of evaporation (gas → liquid) — a common MCQ mix-up. (E) Evaporation rate rises with surface area, temperature and air flow.
June 2024 Paper 11 (Multiple Choice Core) examiner report (0625_s24_er.pdf) Q14: "a significant number of weaker candidates confused condensation and evaporation and incorrectly chose option C." This recurs across multiple years and is a reliable Cambridge MCQ distractor.
SHC definition needs per-kg AND per-°C
A specific heat capacity definition needs two elements: energy per kilogram AND per degree (1 °C). Zero-scoring forms: "energy to heat a substance by 1 °C" (no per-kg); "energy per kilogram" (no temperature); "heat capacity" (that is J/°C). (E) For latent heat, never say it "causes a temperature change" — temperature stays constant.
Consistent across Cambridge 0625 mark scheme conventions for 2.2 definition questions. November 2024 Paper 41 mark scheme (0625_w24_ms_41.pdf) confirms c = E/(mΔθ) form and explicitly marks "energy per kilogram per degree" as the complete definition.
Temperature does not rise during melting
At the melting/boiling point the temperature stays constant while energy is still supplied — the most-tested misconception here. The energy breaks intermolecular bonds, not particle KE, so temperature (average KE) does not rise. On a heating curve, slopes = temperature rising, plateaux = change of state. "Temperature increases during melting" scores zero.
June 2024 Paper 23 examiner report (0625_s24_er.pdf) Q14: "Most weaker candidates incorrectly thought that the temperature rises during this change in state and therefore chose option B or D." November 2023 Paper 12 Q15: "Option A was the most popular choice, whereas Syllabus statement 2.2.3.1 states quite clearly that there is no temperature change during melting." Confirmed across both June 2024 and November 2023 — this is a persistent, high-frequency misconception.
(E) SHC vs specific latent heat
(E) Specific heat capacity (, J/(kg °C)) applies when temperature changes within one state — . Specific latent heat (, J/kg) applies during a change of state at constant temperature — . On a heating curve, sloped sections use and flat plateaux use .
Convert units, then use E = mcΔθ
SHC questions chain ( in seconds) with . Convert first: minutes → seconds (×60), grams → kg (÷1000), and use = final − initial. Write each formula, substitute with units, and give a unit — Cambridge marks the unit separately.
Sketch heating curves with flat plateaux
On a temperature–time sketch, label both axes (temperature / °C; time / s) and draw a horizontal plateau at each change of state. Ice → steam needs two plateaux (0 °C and 100 °C), the boiling one longer. A smooth curve with no flats loses the plateau marks.
Rearrange before you substitute numbers
To find or , rearrange algebraically first: or . Write it before substituting — this earns the method mark even if the arithmetic slips. Inverting it gives an answer far too small.
| Quantity | Formula | Symbol definitions | Unit |
|---|---|---|---|
| Specific heat capacity | = energy (J), = mass (kg), = specific heat capacity (J/(kg °C)), = temperature change (°C or K) | J/(kg °C) | |
| Energy from heater | = power (W), = time (seconds, not minutes) | J | |
| Kelvin conversion | = Kelvin temperature, = Celsius temperature | K | |
| (E) Specific latent heat | = specific latent heat (J/kg) | J |
Mark-scheme definitions:
Specific heat capacity: the energy required to raise the temperature of 1 kg of a substance by 1 °C. Both elements — per kilogram AND per degree Celsius — must be stated for full marks. Unit: J/(kg °C).
(E) Specific latent heat: the energy required to change the state of 1 kg of a substance without a change in temperature. Unit: J/kg.
Define specific heat capacity.
Describe the differences between boiling and evaporation.
Your answer should include reference to where each process occurs and the temperatures at which each process can take place.
(3 marks)