Four classes of oxide
Oxides fall into four classes. Acidic oxides are non-metal oxides (CO₂, SO₂, SO₃, NO₂) that react with alkalis to give a salt and water, and often dissolve to form an acid. Basic oxides are metal oxides (Na₂O, CaO, MgO, CuO) that react with acids to give salt and water. Amphoteric oxides (Al₂O₃, ZnO) react with both, salt and water. Neutral oxides (CO, NO, H₂O) react with neither. Rule: non-metal oxides acidic, metal oxides basic.
Basic oxides + dilute acid
Every basic metal oxide follows metal oxide + acid → salt + water, with no gas. Named reactions with dilute hydrochloric acid: Na₂O + 2HCl → 2NaCl + H₂O; CaO + 2HCl → CaCl₂ + H₂O; MgO + 2HCl → MgCl₂ + H₂O; CuO + 2HCl → CuCl₂ + H₂O; ZnO + 2HCl → ZnCl₂ + H₂O. In each the solid dissolves to a colourless solution (blue for copper), and no bubbling occurs. Note ZnO + HCl gives ZnCl₂ and water, never hydrogen — oxide reactions do not release hydrogen.
(Extended) Amphoteric oxides
(Extended) Al₂O₃ and ZnO are amphoteric: each reacts with acids (as a base) and with alkalis (as an acid), giving a salt and water both ways. Zinc oxide: ZnO + H₂SO₄ → ZnSO₄ + H₂O (acid) and ZnO + 2NaOH → Na₂ZnO₂ + H₂O (alkali), the salt being sodium zincate. Aluminium oxide: Al₂O₃ + 6HCl → 2AlCl₃ + 3H₂O (acid) and Al₂O₃ + 2NaOH → 2NaAlO₂ + H₂O (alkali), giving sodium aluminate. Amphoteric means it acts as both acid and base — not that it is neutral.
Drawn from real examiner reports.
Oxide + acid gives no gas
A metal oxide with acid gives a salt and water only — no gas, no fizzing. The trap is copying the metal reaction: Zn + HCl fizzes and releases hydrogen, but ZnO + HCl merely dissolves the solid to a colourless solution. Hydrogen or oxygen from ZnO + HCl is impossible — an oxide has no hydrogen to give. For an observation write "solid dissolves, no bubbles".
W22 P31 Q6(a); W22 P32 Q6(a)
Observations, not product names
"Describe what is observed" is marked on visible changes, not names of products. For CuO + dilute H₂SO₄ write "the black solid dissolves to give a blue solution"; "copper(II) sulfate is formed" scores zero — it names a product. For any basic oxide + acid: the solid dissolves; the solution may turn coloured (blue for Cu²⁺); no gas forms.
W22 P31 Q6(a); W22 P32 Q6(a)
Amphoteric ≠ neutral
Amphoteric and neutral are opposites. Neutral oxides (CO, NO, H₂O) react with neither acids nor alkalis; amphoteric oxides (ZnO, Al₂O₃) react with both. "Zinc oxide is neutral because it reacts with both and they cancel" is wrong and scores zero. Correct: ZnO reacts with acids to a salt and water (as a base) and with alkalis to a salt and water (as an acid).
Carbon monoxide is neutral
Carbon monoxide (CO) is a neutral oxide — it does not react with acids or alkalis and does not form an acidic solution. Candidates wrongly call it acidic because carbon also forms CO₂, which is acidic; but CO and CO₂ are different oxides with different behaviour. The other neutral oxides to remember are water (H₂O) and nitrogen monoxide (NO).
Get the salt formula and balancing right
Wrong ionic charges break oxide equations. Copper, magnesium, zinc and calcium are 2+, so their chlorides are CuCl₂, MgCl₂, ZnCl₂, CaCl₂ (not CuCl or CaCl), and each needs 2HCl. Aluminium is 3+: Al₂O₃ has two Al, so it needs 6HCl to give 2AlCl₃ + 3H₂O. Sodium is 1+, so Na₂O gives 2NaCl. Set the formula from the ion charge first, then balance.
Answer the command word
Oxide questions use four command words. "State the type" wants one word — acidic, basic, amphoteric or neutral. "Describe what is observed" wants visible changes only, never product names. "Write an equation" wants it balanced with state symbols. "Explain" wants a reason.
Building an oxide equation
Start from the pattern for the oxide type: metal oxide + acid → salt + water, or acidic oxide + alkali → salt + water. Put in correct formulae (set ion charges first), balance, then add state symbols — solid oxide, aqueous acid and salt, liquid water.
Classify by testing with acid and alkali
To classify an unknown oxide, test it with a dilute acid and with an alkali. Reacts with acid only → basic; with alkali only → acidic; with both → amphoteric; with neither → neutral. Back it up with the evidence, e.g. "dissolves in both dilute HCl and NaOH, so amphoteric".
An oxide is a compound containing oxygen and one other element only.
Oxides are classified by how they react with acids and alkalis:
| Type | Definition | Typical examples |
|---|---|---|
| Acidic oxide | Reacts with alkalis to form a salt and water; often dissolves in water to give an acidic solution | , , , |
| Basic oxide | Reacts with acids to form a salt and water; does NOT react with alkalis | , , , , (also amphoteric) |
| Amphoteric oxide | Reacts with both dilute acids AND alkalis to form a salt and water | , |
| Neutral oxide | Reacts with neither acids nor alkalis; does not dissolve to give acidic/alkaline solution | , , |
General pattern: non-metal oxides tend to be acidic; metal oxides tend to be basic; oxides of elements on the metal/non-metal boundary (Al, Zn) tend to be amphoteric.
Mark-scheme two-element definitions:
Define an acidic oxide.
Write the balanced equation, including state symbols, for the reaction of calcium oxide with dilute hydrochloric acid.
[2 marks]